{"id":64893,"date":"2008-02-06T00:00:00","date_gmt":"2008-02-06T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/fragmentacion-radicalaria-de-hemiacetales-anomericos-de-carbohidratos-sa%c2%adntesis-de-nuevos-sintones-fluorados-quirales\/"},"modified":"2008-02-06T00:00:00","modified_gmt":"2008-02-06T00:00:00","slug":"fragmentacion-radicalaria-de-hemiacetales-anomericos-de-carbohidratos-sa%c2%adntesis-de-nuevos-sintones-fluorados-quirales","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica-de-los-hidratos-de-carbono\/fragmentacion-radicalaria-de-hemiacetales-anomericos-de-carbohidratos-sa%c2%adntesis-de-nuevos-sintones-fluorados-quirales\/","title":{"rendered":"Fragmentaci\u00f3n radicalaria de hemiacetales anom\u00e9ricos de carbohidratos: s\u00edntesis de nuevos sintones fluorados quirales"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Nieves Mar\u00eda Rodr\u00edguez Paz <\/strong><\/h2>\n<p>En esta memoria, se ha desarrollado una nueva metodolog\u00eda para la s\u00edntesis de 1-desoxi-1-fluoro-1-halo-1-yodo-alditoles. Para ello, se ha partido de una de 2-fluoro-glicales, a los que se han tratado con distintos agentes halogenantes (n-clorosuccinimida, n-bromoacetamida, selectfl\u00faor y n-yodosuccinimida) para la formaci\u00f3n de diversas dihalohidrinas, que fueron sometidas a la reacci\u00f3n de beta-fragmentaci\u00f3n de radicales alcoxilos anom\u00e9ricos de carbohidratos dando como resultado los 1-desoxi-1-fluoro-1-halo-1-yodo-alditoles deseados con buenos rendimientos. as\u00ed mismo, se llev\u00f3 a cabo la evaluaci\u00f3n de la reactividad de estos sintones aplicando b\u00e1sicamente reacciones radicalarias, lo que nos permite la formaci\u00f3n de nuevas mol\u00e9culas m\u00e1s elaboradas con inter\u00e9s sint\u00e9tico. por \u00faltimo, se ha extendido la estrategia empleada a la elaboraci\u00f3n de 1-desoxi-1,1-dihalo-1-yodo-alditoles no fluorados.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Fragmentaci\u00f3n radicalaria de hemiacetales anom\u00e9ricos de carbohidratos: s\u00edntesis de nuevos sintones fluorados quirales<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Fragmentaci\u00f3n radicalaria de hemiacetales anom\u00e9ricos de carbohidratos: s\u00edntesis de nuevos sintones fluorados quirales <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Nieves Mar\u00eda Rodr\u00edguez Paz <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 La laguna<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 02\/06\/2008<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Cosme Garc\u00eda Francisco<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: victor sotero Martin garcia <\/li>\n<li>Jos\u00e9 Manuel Concell\u00f3n gracia (vocal)<\/li>\n<li>sergio Castillon miranda (vocal)<\/li>\n<li>mercedes Cueto prieto (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Nieves Mar\u00eda Rodr\u00edguez Paz En esta memoria, se ha desarrollado una nueva metodolog\u00eda para la s\u00edntesis de [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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