{"id":67509,"date":"2018-03-09T22:55:55","date_gmt":"2018-03-09T22:55:55","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/transposicion-23-sigmatropica-de-3-sulfinil-dihidropiranos-aproximaciones-sinteticas-a-la-disiherbaina-y-al-acido-pseudomonico-b\/"},"modified":"2018-03-09T22:55:55","modified_gmt":"2018-03-09T22:55:55","slug":"transposicion-23-sigmatropica-de-3-sulfinil-dihidropiranos-aproximaciones-sinteticas-a-la-disiherbaina-y-al-acido-pseudomonico-b","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica-organica\/transposicion-23-sigmatropica-de-3-sulfinil-dihidropiranos-aproximaciones-sinteticas-a-la-disiherbaina-y-al-acido-pseudomonico-b\/","title":{"rendered":"Transposici\u00f3n (2,3)-sigmatr\u00f3pica de 3-sulfinil dihidropiranos: aproximaciones sint\u00e9ticas a la disiherbaina y al \u00e1cido pseudom\u00f3nico b"},"content":{"rendered":"

Tesis doctoral de Nadia Lwoff Ivanissevich <\/strong><\/h2>\n

Cap\u00edtulo 1: introducci\u00f3n general 3 cap\u00edtulo 2: s\u00edntesis enantioselectiva de sulfinil y sulfoximinoil dihidropiranos 2.1. Introducci\u00f3n 13 2.2. Antecedentes generales 14 2.3. Antecedentes del grupo de trabajo 21 2.4. Objetivos 25 2.5. S\u00edntesis de productos de partida 26 2.6. Discusi\u00f3n de resultados 29 2.7. Asignaci\u00f3n estructural 50 2.8. Conclusiones 55 2.9. Parte experimental 57 cap\u00edtulo 3: estudio de la transposici\u00f3n sigmatr\u00f3pica de sulfinil dihidropiranos. Aplicaciones sint\u00e9ticas 3.1. Introducci\u00f3n 103 3.2. Estudio de la transposici\u00f3n sigmatr\u00f3pica de 3-sulfinil dihidropiranos 104 3.2.1. Antecedentes generales 104 3.2.2. Antecedentes del grupo de trabajo 112 3.2.3. Objetivos 112 3.2.4. Discusi\u00f3n de resultados 113 3.2.5. Asignaci\u00f3n estructural 124 3.3. Aplicaciones sint\u00e9ticas: s\u00edntesis formal de ent-disiherbaina y del esqueleto de desoximalayamicina a 128 3.3.1. Antecedentes generales 128 3.3.2. Antecedentes del grupo de trabajo 143 3.3.3. Objetivos 144 3.3.4. Discusi\u00f3n de resultados 145 3.4. Conclusiones 152 3.5. Parte experimental 154 cap\u00edtulo 4: estudio de la reactividad de 3-dihidropiranoles. Aplicaciones sint\u00e9ticas 4.1. Introducci\u00f3n 201 4.2. Estudio de la reactividad de 3-dihidropiranoles 202 4.2.1. Antecedentes generales 202 4.2.2. Objetivos 217 4.2.3. S\u00edntesis de productos de partida 218 4.2.4. Discusi\u00f3n de resultados 220 4.2.5. Asignaci\u00f3n estructural 227 4.3. Aplicaciones sint\u00e9ticas: s\u00edntesis total de metil y etil desoxipseudomonatos b 228 4.3.1. Antecedentes generales 229 4.3.2. Discusi\u00f3n de resultados 240 4.4. Conclusiones 249 4.5. Parte experimental 251<\/p>\n

 <\/p>\n

Datos acad\u00e9micos de la tesis doctoral \u00abTransposici\u00f3n (2,3)-sigmatr\u00f3pica de 3-sulfinil dihidropiranos: aproximaciones sint\u00e9ticas a la disiherbaina y al \u00e1cido pseudom\u00f3nico b<\/strong>\u00ab<\/h3>\n
    \n
  • T\u00edtulo de la tesis:<\/strong>\u00a0 Transposici\u00f3n (2,3)-sigmatr\u00f3pica de 3-sulfinil dihidropiranos: aproximaciones sint\u00e9ticas a la disiherbaina y al \u00e1cido pseudom\u00f3nico b <\/li>\n
  • Autor:<\/strong>\u00a0 Nadia Lwoff Ivanissevich <\/li>\n
  • Universidad:<\/strong>\u00a0 Aut\u00f3noma de Madrid<\/li>\n
  • Fecha de lectura de la tesis:<\/strong>\u00a0 17\/10\/2008<\/li>\n<\/ul>\n

     <\/p>\n

    Direcci\u00f3n y tribunal<\/h3>\n
      \n
    • Director de la tesis<\/strong>\n
        \n
      • Fern\u00e1ndez De La Pradilla S\u00e1inz De Aja Roberto<\/li>\n<\/ul>\n<\/li>\n
      • Tribunal<\/strong>\n
          \n
        • Presidente del tribunal: Mar\u00eda del carmen Carre\u00f1o garcia <\/li>\n
        • josep Bonjoch sese (vocal)<\/li>\n
        • Fernando Aznar gomez (vocal)<\/li>\n
        • pere de March centelles (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n

           <\/p>\n","protected":false},"excerpt":{"rendered":"

          Tesis doctoral de Nadia Lwoff Ivanissevich Cap\u00edtulo 1: introducci\u00f3n general 3 cap\u00edtulo 2: s\u00edntesis enantioselectiva de sulfinil y sulfoximinoil dihidropiranos […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[416],"tags":[57825,21277,1417,29244,148468,13656],"class_list":["post-67509","post","type-post","status-publish","format-standard","hentry","category-quimica-organica","tag-fernandez-de-la-pradilla-sainz-de-aja-roberto","tag-fernando-aznar-gomez","tag-josep-bonjoch-sese","tag-maria-del-carmen-carreno-garcia","tag-nadia-lwoff-ivanissevich","tag-pere-de-march-centelles"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/67509","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=67509"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/67509\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=67509"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=67509"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=67509"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}