{"id":71795,"date":"2018-03-09T23:16:29","date_gmt":"2018-03-09T23:16:29","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sintesis-de-metabocitos-de-origen-marino\/"},"modified":"2018-03-09T23:16:29","modified_gmt":"2018-03-09T23:16:29","slug":"sintesis-de-metabocitos-de-origen-marino","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sintesis-de-metabocitos-de-origen-marino\/","title":{"rendered":"Sintesis de metabocitos de origen marino"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Alberto Diego Taboada <\/strong><\/h2>\n<p>La s\u00edntesis de compuestos bioactivos a partir de productos naturales abundantes es una de las l\u00edneas  de trabajo abordadas en nuestro grupo de investigaci\u00f3n. el presente trabajo puede encuadrarse dentro de dicha l\u00ednea de investigaci\u00f3n por ello se han escogido los siguientes objetivos de s\u00edntesis: \u00e1cido sub\u00e9rsico, hyrtiosal, salmahyrtisol a. La s\u00edntesis de estos tres compuestos objetivo se ha realizado a partir de un producto natural abundante como es el esclareol. a partir de esclareol y \u00e1cido p-hidroxibenzoico se ha sintetizado \u00e1cido (+)-sub\u00e9rsico, enanti\u00f3mero del producto natural \u00e1cido (-)-sub\u00e9rsico quedando as\u00ed determinada la estereoqu\u00edmica de este \u00faltimo. La s\u00edntesis de hyrtiosal y su ep\u00edmero en la posici\u00f3n 16 se ha llevado a cabo a partir de esclareol. se ha puesto a punto la reacci\u00f3n de reordenamiento de un ep\u00f3xiderivado con esqueleto isoanticopalano hasta el aldeh\u00eddo que contiene el fragmento izquierdo de esqueleto hyrtiosano. La s\u00edntesis de (-)-hyrtiosal ha permitido determinar la configuraci\u00f3n absoluta de este nuevo sesterterpeno que posee un nuevo esqueleto hyrtiosano, mediante el m\u00e9todo de mosher. Es importante rese\u00f1ar que es la primera vez que se describe la s\u00edntesis de compuestos con esqueleto hyrtiosano.  la s\u00edntesis de salmahyrtisol a se ha llevado a cabo a partir de (-)-hyrtiosal. para ello se ha puesto a punto la reacci\u00f3n de ciclaci\u00f3n que ha conducido a compuestos de esqueleto salmahyrtisano y que ha permitido la s\u00edntesis de 18-epi-salmahyrtisol a. Por una ruta an\u00e1loga a partir de 16-epi-hyrtiosal se ha obtenido 15,18-di-epi-salmahyrtisol a. Estos dos compuestos son estereois\u00f3meros del producto natural. Ante la imposibilidad de obtener el producto natural a partir de su precursor biogen\u00e9tico hyrtiosal, se ha iniciado una nueva ruta sint\u00e9tica hacia la s\u00edntesis de salmahyrtisol a.  la s\u00edntesis de compuestos bioactivos a partir de productos naturales abundantes es una de las l\u00edneas  de<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Sintesis de metabocitos de origen marino<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Sintesis de metabocitos de origen marino <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Alberto Diego Taboada <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Salamanca<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 13\/12\/2004<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Pilar Basabe Barcala<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: arturo San feliciano martin <\/li>\n<li>vicente Gotor santamar\u00eda (vocal)<\/li>\n<li>benjam\u00edn Rodr\u00edguez gonz\u00e1lez (vocal)<\/li>\n<li>Andr\u00e9s Garcia granado lopez del hierro (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Alberto Diego Taboada La s\u00edntesis de compuestos bioactivos a partir de productos naturales abundantes es una de [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[21525,239,6775,17,21005,416,9386],"tags":[156329,1653,3425,9621,65371,6659],"class_list":["post-71795","post","type-post","status-publish","format-standard","hentry","category-hidrocarburos-aromaticos","category-mecanismos-de-las-reacciones-organicas","category-organometalicos","category-quimica","category-quimica-de-iones-carbonio","category-quimica-organica","category-salamanca","tag-alberto-diego-taboada","tag-andres-garcia-granado-lopez-del-hierro","tag-arturo-san-feliciano-martin","tag-benjamin-rodriguez-gonzalez","tag-pilar-basabe-barcala","tag-vicente-gotor-santamaria"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/71795","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=71795"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/71795\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=71795"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=71795"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=71795"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}