{"id":73248,"date":"2018-03-09T23:18:06","date_gmt":"2018-03-09T23:18:06","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sobre-la-sa%c2%adntesis-estructura-y-reactividad-de-complejos-metal-carbeno-un-estudio-teorico-experimental\/"},"modified":"2018-03-09T23:18:06","modified_gmt":"2018-03-09T23:18:06","slug":"sobre-la-sa%c2%adntesis-estructura-y-reactividad-de-complejos-metal-carbeno-un-estudio-teorico-experimental","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sobre-la-sa%c2%adntesis-estructura-y-reactividad-de-complejos-metal-carbeno-un-estudio-teorico-experimental\/","title":{"rendered":"Sobre la s\u00edntesis, estructura y reactividad de complejos metal-carbeno: un estudio te\u00f3rico-experimental"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Israel Fern\u00e1ndez L\u00f3pez <\/strong><\/h2>\n<p>El trabajo realizado durante la tesis doctoral se enmarca dentro del campo de la qu\u00edmica organomet\u00e1lica y su aplicaci\u00f3n al desarrollo de nuevos procesos en s\u00edntesis org\u00e1nica. Concretamente, dicho trabajo se ha centrado en el estudio de complejos metal-carbeno de tipo fischer del grupo 6, sustratos de probada versatilidad en s\u00edntesis org\u00e1nica.  los aspectos m\u00e1s relevantes de dicha tesis son, a grandes rasgos, los siguientes:  * estudio te\u00f3rico-experimental de la reactividad fotoqu\u00edmica de complejos metal-carbeno de tipo fischer. En este trabajo se han utilizado m\u00e9todos de c\u00e1lculo avanzados junto con soporte experimental para determinar el mecanismo de la reacci\u00f3n de fotocarbonilaci\u00f3n de dichos complejos, su reactividad fotoqu\u00edmica frente a iminas (para la generaci\u00f3n de beta-lactamas) y para la b\u00fasqueda de nuevas formas alternativas de reactividad fotoqu\u00edmica. Este trabajo ha conducido a la propuesta de un mecanismo general para la reacci\u00f3n de dichos complejos con iminas, descubriendo un proceso de reordenamiento 1,3-metalotr\u00f3pico (proceso bastante com\u00fan en la qu\u00edmica de estos complejos). por \u00faltimo, se ha descubierto una nueva forma de reactividad fotoqu\u00edmica que consiste en un reordenamiento 1,2-diotr\u00f3pico de tipo i y que es compatible con todo tipo de complejos metal-carbeno del grupo 6.  * dise\u00f1o, s\u00edntesis y estudio de la reactividad de nuevos complejos metal-carbeno con estructuras conformacionalmente retringidas. En este caso, se han sintetizado distintos tipos de complejos con estructuras cilof\u00e1nicas y macroc\u00edclicas, dif\u00edciles de obtener por m\u00e9todos convencionales. Las propiedades electroqu\u00edmicas y la reactividad particular de estos complejos los convierten en unos candidatos importantes para su futura aplicaci\u00f3n en el campo de la qu\u00edmica supramolecular y ciencia de nuevos materiales metal-org\u00e1nicos.  * estudio te\u00f3rico-experimental del comportamiento de complejos metal-carbono de fischer en pr<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Sobre la s\u00edntesis, estructura y reactividad de complejos metal-carbeno: un estudio te\u00f3rico-experimental<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Sobre la s\u00edntesis, estructura y reactividad de complejos metal-carbeno: un estudio te\u00f3rico-experimental <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Israel Fern\u00e1ndez L\u00f3pez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Complutense de Madrid<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 16\/03\/2005<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Sierra Rodr\u00edguez Miguel \u00e1ngel<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: joaquin Plumet ortega <\/li>\n<li>Jes\u00fas Jim\u00e9nez-barbero (vocal)<\/li>\n<li> Cossio mora Fernando p. (vocal)<\/li>\n<li> Mascarenas cid Jos\u00e9 Luis (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Israel Fern\u00e1ndez L\u00f3pez El trabajo realizado durante la tesis doctoral se enmarca dentro del campo de la [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[17,416],"tags":[48740,159061,43719,1652,159062,25474],"class_list":["post-73248","post","type-post","status-publish","format-standard","hentry","category-quimica","category-quimica-organica","tag-cossio-mora-fernando-p","tag-israel-fernandez-lopez","tag-jesus-jimenez-barbero","tag-joaquin-plumet-ortega","tag-mascarenas-cid-jose-luis","tag-sierra-rodriguez-miguel-angel"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/73248","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=73248"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/73248\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=73248"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=73248"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=73248"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}