{"id":73786,"date":"2018-03-09T23:18:42","date_gmt":"2018-03-09T23:18:42","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/reactividad-de-clusters-trinucleares-de-rutenio-derivados-de-hidrazinas\/"},"modified":"2018-03-09T23:18:42","modified_gmt":"2018-03-09T23:18:42","slug":"reactividad-de-clusters-trinucleares-de-rutenio-derivados-de-hidrazinas","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/reactividad-de-clusters-trinucleares-de-rutenio-derivados-de-hidrazinas\/","title":{"rendered":"Reactividad de clusters trinucleares de rutenio derivados de hidrazinas."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Lorena Martinez Mendez <\/strong><\/h2>\n<p>La presente memoria describe la reactividad de fosfinas y alquinos frente a clusters carbon\u00edlicos trinucleares de rutenio derivados de hidrazinas. en primer lugar se describen las reacciones de sustituci\u00f3n de ligandos carbonilo por fosfinas en el complejo [ru3(\u00c2\u00b5-h)(\u00c2\u00b53, 2-hnnme2)(co)9] y en su derivado protonado [ru3(\u00c2\u00b5-h)2(\u00c2\u00b53, 2-hnnme2)(co)9][bf4]. A continuaci\u00f3n, se aborda la reactividad de los complejos [ru3(\u00c2\u00b5-h)(\u00c2\u00b53, 2-hnnme2)(co)9] y [ru3(\u00c2\u00b5-h)(\u00c2\u00b53, 2-mennhme)(co)9] frente a alquinos y diinos. En todos los casos se han obtenido derivados con ligandos alquenilo o inenilo mediante procesos cuya selectividad est\u00e1 influenciada, tanto por la naturaleza del ligando nitrogenado, como por la del reactivo utilizado. Algunos resultados experimentales se han racionalizado comparando las energ\u00edas absolutas de los compuestos involucrados (calculadas mediante m\u00e9todos dft). Finalmente, esta memoria recoge tambi\u00e9n un estudio de la reactividad de algunos de los derivados alquenilo obtenidos frente a alquinos y diinos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Reactividad de clusters trinucleares de rutenio derivados de hidrazinas.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Reactividad de clusters trinucleares de rutenio derivados de hidrazinas. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Lorena Martinez Mendez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Oviedo<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 29\/04\/2005<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Cabeza De Marco JavierAngel<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: victor Riera gonz\u00e1lez <\/li>\n<li> Valerga jimenez pedro s. (vocal)<\/li>\n<li>georg Suss fink (vocal)<\/li>\n<li>f\u00e9lix angel Jal\u00f3n sot\u00e9s (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Lorena Martinez Mendez La presente memoria describe la reactividad de fosfinas y alquinos frente a clusters carbon\u00edlicos [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[863,1116,8846,17,20],"tags":[79550,51030,160084,160082,160083,18475],"class_list":["post-73786","post","type-post","status-publish","format-standard","hentry","category-compuestos-organometalicos","category-estructura-de-los-compuestos-inorganicos","category-oviedo","category-quimica","category-quimica-inorganica","tag-cabeza-de-marco-javierangel","tag-felix-angel-jalon-sotes","tag-georg-suss-fink","tag-lorena-Martinez-mendez","tag-valerga-jimenez-pedro-s","tag-victor-riera-gonzalez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/73786","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=73786"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/73786\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=73786"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=73786"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=73786"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}