{"id":78724,"date":"2018-03-09T23:24:27","date_gmt":"2018-03-09T23:24:27","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/nuevas-perspectivas-con-complejos-carbeno-de-fisher-carbenos-soportados-enantiopuros\/"},"modified":"2018-03-09T23:24:27","modified_gmt":"2018-03-09T23:24:27","slug":"nuevas-perspectivas-con-complejos-carbeno-de-fisher-carbenos-soportados-enantiopuros","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/nuevas-perspectivas-con-complejos-carbeno-de-fisher-carbenos-soportados-enantiopuros\/","title":{"rendered":"Nuevas perspectivas con complejos carbeno de fisher carbenos soportados enantiopuros"},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Prado Gonz\u00e1lez Ana De <\/strong><\/h2>\n<p>La presente memoria se ha dividido en tres cap\u00edtulos de acuerdo con los tres grandes temas en los que se ha estudiado la participaci\u00f3n de los complejos carbenos de fischer: s\u00edntesis sobre soportes polim\u00e9ricos, s\u00edntesis esteroselectividad y formaci\u00f3n y reactividad de carbenos de fisher no estabilizados.  en el primer cap\u00edtulo se describen la primera s\u00edntesis, directamente sobre un soporte polim\u00e9rica, de complejos carbeno de fischer. Adem\u00e1s, se ha puesto de manifiesto la participaci\u00f3n de los sistemas pol\u00edmero-carbeno obtenidos, en una reacci\u00f3n e cilopropanaci\u00f3n, siendo posible la regeneraci\u00f3n del sistema para involucrarlo en un segundo ciclo de s\u00edntesis.  en el segundo cap\u00edtulo se recoge la s\u00edntesis de tres nuevos alcoxicarbenos de fisher enantiom\u00e9ricamente puros y su participaci\u00f3n en reacciones de s\u00edntesis diastereoselectiva. De este modo se describen los procesos diels-alder, mukaiyama-michael o carbociclaciones [2+1] que conducen a compuestos enantiom\u00e9ricamente puros derivados del norborneno, ?-Butenolidas y ciclopropanos altamente funcionalizados, respectivamente.  finalmente, en el \u00faltimo cap\u00edtulo se describe la s\u00edntesis, caracterizaci\u00f3n espectrosc\u00f3pica y reactividad preliminar del primer alquenilcarbeno de fischer no estabilizado por hetero\u00e1tomo de un metal de transici\u00f3n del grupo 6. Los estudios realizados para la consecuci\u00f3n final de la s\u00edntesis del carbeno no estabilizado ha puesto de manifiesto la existencia de intermedios altamente reactivos con distintos patrones de reactividad en funci\u00f3n de las condiciones del proceso lo que puede ser aprovechado para el acceso a nuevas estructuras.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Nuevas perspectivas con complejos carbeno de fisher carbenos soportados enantiopuros<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Nuevas perspectivas con complejos carbeno de fisher carbenos soportados enantiopuros <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Prado Gonz\u00e1lez Ana De <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Oviedo<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 17\/02\/2006<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Jos\u00e9 Joaquin Barluenga Mur<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: julio \u00e1lvarez-builla g\u00f3mez <\/li>\n<li> Sierra rodr\u00edguez Miguel angel (vocal)<\/li>\n<li>santos Fustero lardi\u00e9s (vocal)<\/li>\n<li>v. Javier Gar\u00edn tercero (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Prado Gonz\u00e1lez Ana De La presente memoria se ha dividido en tres cap\u00edtulos de acuerdo con los [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[645,6775,8846,17,416],"tags":[3282,762,169148,18907,25474,7339],"class_list":["post-78724","post","type-post","status-publish","format-standard","hentry","category-hidrocarburos-alifaticos","category-organometalicos","category-oviedo","category-quimica","category-quimica-organica","tag-jose-joaquin-barluenga-mur","tag-julio-alvarez-builla-gomez","tag-prado-gonzalez-ana-de","tag-santos-fustero-lardies","tag-sierra-rodriguez-miguel-angel","tag-v-javier-garin-tercero"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/78724","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=78724"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/78724\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=78724"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=78724"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=78724"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}