{"id":80291,"date":"1999-02-07T00:00:00","date_gmt":"1999-02-07T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sintesis-y-caracterizacion-de-nuevos-complejos-de-rutenio-conteniendo-el-ligando-hidrotris-pirazolil-borato-y-fosfinas-voluminosas\/"},"modified":"1999-02-07T00:00:00","modified_gmt":"1999-02-07T00:00:00","slug":"sintesis-y-caracterizacion-de-nuevos-complejos-de-rutenio-conteniendo-el-ligando-hidrotris-pirazolil-borato-y-fosfinas-voluminosas","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sintesis-y-caracterizacion-de-nuevos-complejos-de-rutenio-conteniendo-el-ligando-hidrotris-pirazolil-borato-y-fosfinas-voluminosas\/","title":{"rendered":"Sintesis y caracterizaci\u00f3n de nuevos complejos de rutenio conteniendo el ligando hidrotris (pirazolil) borato y fosfinas voluminosas"},"content":{"rendered":"

Tesis doctoral de Miguel Angel Jimenez Tenorio <\/strong><\/h2>\n

El ligando hidrotris (pirazolil) borato (tp) presenta bastantes similitudes con los ligandos ciclopentadienilo (cp) y pentametilciclopentadienilo (cp*), sin embargo, tambi\u00e9n existen diferencias notables que van a condicionar la qu\u00edmica de los distintos complejos formados por ellos. se han sintetizado un buen n\u00famero de nuevos complejos de rutenio conteniendo el ligando hidrotris (pirazolil) borato y distintas fosfinas voluminosas (ipr2pch2ch2pipr2, pet3, pmeipr2) y se ha realizado un estudio comparativo con otros complejos semi-sandwich de este metal conteniendo los ligandos cp y cp*. el trabajo se ha dividido en dos partes: – en la primera se aborda la s\u00edntesis de nuevos cloro e hidruro complejos y se estudia su interacci\u00f3n con mol\u00e9culas peque\u00f1as (h2, n2, co, cnbut, etc.). – en la segunda se estudia la reactividad de estas especies frente alquinos y alquinoles, con especial atenci\u00f3n a algunas reacciones de acoplamiento que dan lugar a la formaci\u00f3n de nuevos enlaces c-c.<\/p>\n

 <\/p>\n

Datos acad\u00e9micos de la tesis doctoral \u00abSintesis y caracterizaci\u00f3n de nuevos complejos de rutenio conteniendo el ligando hidrotris (pirazolil) borato y fosfinas voluminosas<\/strong>\u00ab<\/h3>\n
    \n
  • T\u00edtulo de la tesis:<\/strong>\u00a0 Sintesis y caracterizaci\u00f3n de nuevos complejos de rutenio conteniendo el ligando hidrotris (pirazolil) borato y fosfinas voluminosas <\/li>\n
  • Autor:<\/strong>\u00a0 Miguel Angel Jimenez Tenorio <\/li>\n
  • Universidad:<\/strong>\u00a0 C\u00e1diz<\/li>\n
  • Fecha de lectura de la tesis:<\/strong>\u00a0 02\/07\/1999<\/li>\n<\/ul>\n

     <\/p>\n

    Direcci\u00f3n y tribunal<\/h3>\n
      \n
    • Director de la tesis<\/strong>\n
        \n
      • Manuel Jimenez Tenorio<\/li>\n<\/ul>\n<\/li>\n
      • Tribunal<\/strong>\n
          \n
        • Presidente del tribunal: Luis Antonio Oro giral <\/li>\n
        • seraf\u00edn Bernal m\u00e1rquez (vocal)<\/li>\n
        • ernesto Carmona guzm\u00e1n (vocal)<\/li>\n
        • jaume Granell sanvicente (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n

           <\/p>\n","protected":false},"excerpt":{"rendered":"

          Tesis doctoral de Miguel Angel Jimenez Tenorio El ligando hidrotris (pirazolil) borato (tp) presenta bastantes similitudes con los ligandos ciclopentadienilo […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[1506,863,17,20],"tags":[1386,49685,29005,69001,172023,19449],"class_list":["post-80291","post","type-post","status-publish","format-standard","hentry","category-cadiz","category-compuestos-organometalicos","category-quimica","category-quimica-inorganica","tag-ernesto-carmona-guzman","tag-jaume-granell-sanvicente","tag-luis-antonio-oro-giral","tag-manuel-jimenez-tenorio","tag-miguel-angel-jimenez-tenorio","tag-serafin-bernal-marquez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/80291","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=80291"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/80291\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=80291"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=80291"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=80291"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}