{"id":81217,"date":"1999-12-11T00:00:00","date_gmt":"1999-12-11T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sa%c2%adntesis-caracterizacion-estructural-y-reactividad-de-complejos-alquil-imido-pentametilciclopentadienil-tantalo-v\/"},"modified":"1999-12-11T00:00:00","modified_gmt":"1999-12-11T00:00:00","slug":"sa%c2%adntesis-caracterizacion-estructural-y-reactividad-de-complejos-alquil-imido-pentametilciclopentadienil-tantalo-v","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sa%c2%adntesis-caracterizacion-estructural-y-reactividad-de-complejos-alquil-imido-pentametilciclopentadienil-tantalo-v\/","title":{"rendered":"S\u00edntesis, caracterizaci\u00f3n estructural y reactividad de complejos alquil imido pentametilciclopentadienil t\u00e1ntalo (v)"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Aurora Castro Correro <\/strong><\/h2>\n<p>Este trabajo recoge las reacciones de alquilaci\u00f3n de complejos dicloro y cloro metil imidopentametilciclopentadienil t\u00e1ntalo (v) que conduce a la formaci\u00f3n de tres series de complejos alquil cloro, dialquil y alquil metil imido pentametilciclopentadienil t\u00e1ntalo (v).  la reacci\u00f3n de los complejos alquil imido con mon\u00f3xido de carbono e isocianuro tiene lugar con inserci\u00f3n en un solo enlace t\u00e1ntalo-carbono originando especies que en algunos casos pueden evolucionar mediante proceos de acoplamiento u otros, y que han permitido establecer uan secuencia que refleja  la tendencia relativa de migraci\u00f3n de diferentes grupos alquilo comparados con el grupo metilo.  complejos dialquil dicloropentametilciclopentadienil t\u00e1ntalo (v) (alquilo me), reaccionan con 2,6-dimetilfenil isocianuro con formaci\u00f3n de complejos relativamente estables alquil dicloro n2-iminoacilo, en contraste, con la formaci\u00f3n del derivado azatantalaciclopropano para el derivado dimetil dicloro.  disoluciones en benceno d6 \u00f3 en n-hexano de los complejos alquil dicloro n2-iminoacilo,se descomponen despu\u00e9s de 12 horas, dando lugar a la formaci\u00f3n del complejo dicloroimido pentametilciclopentadienil t\u00e1ntalo (v).  todos los complejos han sido caracterizados utilizando los m\u00e9todos espectrosc\u00f3picos habituales y en los casos que ha sido posible se ha determinado la estructura molecular por difracci\u00f3n de rayos-x.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>S\u00edntesis, caracterizaci\u00f3n estructural y reactividad de complejos alquil imido pentametilciclopentadienil t\u00e1ntalo (v)<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 S\u00edntesis, caracterizaci\u00f3n estructural y reactividad de complejos alquil imido pentametilciclopentadienil t\u00e1ntalo (v) <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Aurora Castro Correro <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Alcal\u00e1<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 12\/11\/1999<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Manuel G\u00f3mez Rubio<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Jos\u00e9 oriol Rossell alfonso <\/li>\n<li>Jes\u00fas Mar\u00eda Mart\u00ednez de ilarduya mart\u00ednez de ilarduya (vocal)<\/li>\n<li>esther Delgado laita (vocal)<\/li>\n<li>avelino Mart\u00edn alonso (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Aurora Castro Correro Este trabajo recoge las reacciones de alquilaci\u00f3n de complejos dicloro y cloro metil imidopentametilciclopentadienil [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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