{"id":81712,"date":"2018-03-10T00:05:37","date_gmt":"2018-03-10T00:05:37","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sintesis-y-reactividad-de-fosfuro-complejos-organometalicos-del-grupo-6-con-alto-poder-electrofilico\/"},"modified":"2018-03-10T00:05:37","modified_gmt":"2018-03-10T00:05:37","slug":"sintesis-y-reactividad-de-fosfuro-complejos-organometalicos-del-grupo-6-con-alto-poder-electrofilico","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sintesis-y-reactividad-de-fosfuro-complejos-organometalicos-del-grupo-6-con-alto-poder-electrofilico\/","title":{"rendered":"\u00absintesis y reactividad de fosfuro complejos organometalicos del grupo 6 con alto poder electrofilico\u00bb"},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Rueda Lopez M. Teresa <\/strong><\/h2>\n<p>En el trabajo desarrollado se han sitetizado diferentes complejos dinucleares de mo y w con ligandos fosfuros puente y con diferentes ordenes de enlace metal-metal. Dichas especies se generan en reacciones de descarbonilaci\u00f3n, oxidaci\u00f3n y protonaci\u00f3n, aisl\u00e1ndose en alguno de los procesos complejos intermedios de alta reactividad. Entre estos \u00faltimos destacan las especies paramagn\u00e9ticas [m2(   -pph2)cp2(co)4] [m=mo(6.A), w(6.B)], los carbino complejos [m2(   -coh)(   -pph2)2cp2](bf4) [m=mo(13.A), w(13.B)], el hidroxoderivado [w2(   -pph2)2(   2-f2 bf2) cp2(co)](bf4).H2o (21.A). Se ha estudiado la reactividad de estos compuestos frente a diferentes sustratos de naturaleza org\u00e1nica e inorg\u00e1nica, produci\u00e9ndose en el transcurso de la reacci\u00f3n activaciones de enlaces p-h, s-h, o-h, cl-h, c-h, m-m,etc. Tanto en la s\u00edntesis de las especies de partida como en el estudio de su reactividad queda patente la importancia del ligando fosfuro en orden a mantener la unidad dimet\u00e1lica.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>\u00absintesis y reactividad de fosfuro complejos organometalicos del grupo 6 con alto poder electrofilico\u00bb<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 \u00absintesis y reactividad de fosfuro complejos organometalicos del grupo 6 con alto poder electrofilico\u00bb <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Rueda Lopez M. Teresa <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Oviedo<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 16\/12\/1999<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Victor Riera Gonz\u00e1lez<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: ernesto Carmona guzm\u00e1n <\/li>\n<li> Carriedo ule gabino a. (vocal)<\/li>\n<li>g. Connelly neil (vocal)<\/li>\n<li>esther Delgado laita (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Rueda Lopez M. Teresa En el trabajo desarrollado se han sitetizado diferentes complejos dinucleares de mo y [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[6775,8846,17,416],"tags":[25371,1386,10828,174209,174208,18475],"class_list":["post-81712","post","type-post","status-publish","format-standard","hentry","category-organometalicos","category-oviedo","category-quimica","category-quimica-organica","tag-carriedo-ule-gabino-a","tag-ernesto-carmona-guzman","tag-esther-delgado-laita","tag-g-connelly-neil","tag-rueda-lopez-m-teresa","tag-victor-riera-gonzalez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/81712","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=81712"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/81712\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=81712"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=81712"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=81712"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}