{"id":87303,"date":"2018-03-10T00:12:04","date_gmt":"2018-03-10T00:12:04","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/estudio-cinetico-de-reacciones-de-transferencia-protonica-del-grupo-nitroso-y-de-solvolisis-de-cloruros-de-benzoilo-en-diversos-medios\/"},"modified":"2018-03-10T00:12:04","modified_gmt":"2018-03-10T00:12:04","slug":"estudio-cinetico-de-reacciones-de-transferencia-protonica-del-grupo-nitroso-y-de-solvolisis-de-cloruros-de-benzoilo-en-diversos-medios","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/fisica\/estudio-cinetico-de-reacciones-de-transferencia-protonica-del-grupo-nitroso-y-de-solvolisis-de-cloruros-de-benzoilo-en-diversos-medios\/","title":{"rendered":"Estudio cin\u00e9tico de reacciones de transferencia prot\u00f3nica, del grupo nitroso y de solv\u00f3lisis de cloruros de benzoilo en diversos medios"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Jos\u00e9 Antonio De Sousa Moreira <\/strong><\/h2>\n<p>En la tesis doctoral titulada\u00bbestudio cin\u00e9tico de reacciones de transferencia prot\u00f3nica, del grupo nitroso y de solv\u00f3lisis de cloruros de benzoilo en diversos medios\u00bb se ha realizado un estudio mecanicista de las reacciones de transferencia del grupo nitroso desde n-metil-n-nitrosobenceno sulfonamidas y n-metil-nitrosoguanidinas a aminas. Los resultados obtenidos han sido interpretados mediante la aplicaci\u00f3n de la teor\u00eda de marcus desarrollada para reacciones de transferencia electr\u00f3nica. El estudio de las reacciones de transferencia del grupo nitroso se ha continuado investigando la nitrosaci\u00f3n de aminas por nitritos de alquilo en isooctano. La combinaci\u00f3n de la peque\u00f1a capacidad de este disolvente para solvatar cargas y de la baja nucleofilia de las aminas utilizadas ha permitido realizar una observaci\u00f3n directa del intermedio de reacci\u00f3n, construyendo \u00e9sta la primera evidencia directa de formaci\u00f3n de intermedios de adici\u00f3n en reacciones de transferencia del grupo nitroso. El estudio de la reacci\u00f3n de transferencia prot\u00f3nica desde el i\u00f3n 2-acetil-1-metil-piridinio a iones hidroxilo y aminas ha permiito obtener las barreras intr\u00ednsicas de reacci\u00f3n. Los resultados han sido comparados con otros existentes en la bibliograf\u00eda para la formaci\u00f3n de diversos carbaniones y han sido explicados mediante la aplicaci\u00f3n del principio de sincronizaci\u00f3n no perfecta. Finalmente se ha investigado el proceso de solv\u00f3lisis de cloruros de benzoilo en microemulsiones de aot\/issoctano\/agua. Los resultados obtenidos muestran que al variar la composici\u00f3n de la microemulsi\u00f3n se induce un cambio en el mecanismo de estas reacciones.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Estudio cin\u00e9tico de reacciones de transferencia prot\u00f3nica, del grupo nitroso y de solv\u00f3lisis de cloruros de benzoilo en diversos medios<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Estudio cin\u00e9tico de reacciones de transferencia prot\u00f3nica, del grupo nitroso y de solv\u00f3lisis de cloruros de benzoilo en diversos medios <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Jos\u00e9 Antonio De Sousa Moreira <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Santiago de compostela<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 13\/11\/2000<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Leis Fidago Jos\u00e9 Ram\u00f3n<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: julio Casado linarejos <\/li>\n<li>Francisco S\u00e1nchez burgos (vocal)<\/li>\n<li> Norberto Mar\u00eda de f\u00e1tima (vocal)<\/li>\n<li>Jorge Marquet (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Jos\u00e9 Antonio De Sousa Moreira En la tesis doctoral titulada\u00bbestudio cin\u00e9tico de reacciones de transferencia prot\u00f3nica, del [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[2745,199,560,977],"tags":[2750,182794,182791,565,182792,182793],"class_list":["post-87303","post","type-post","status-publish","format-standard","hentry","category-cinetica-quimica","category-fisica","category-quimica-fisica","category-santiago-de-compostela","tag-francisco-sanchez-burgos","tag-jorge-marquet","tag-jose-antonio-de-sousa-moreira","tag-julio-casado-linarejos","tag-leis-fidago-jose-ramon","tag-norberto-maria-de-fatima"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/87303","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=87303"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/87303\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=87303"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=87303"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=87303"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}