{"id":88602,"date":"2018-03-10T00:13:38","date_gmt":"2018-03-10T00:13:38","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sintesis-y-reactividad-e-carbonilos-dinucleares-insaturados-de-metales-de-transicion-conteniendo-ligandos-ciclopentadienilo\/"},"modified":"2018-03-10T00:13:38","modified_gmt":"2018-03-10T00:13:38","slug":"sintesis-y-reactividad-e-carbonilos-dinucleares-insaturados-de-metales-de-transicion-conteniendo-ligandos-ciclopentadienilo","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sintesis-y-reactividad-e-carbonilos-dinucleares-insaturados-de-metales-de-transicion-conteniendo-ligandos-ciclopentadienilo\/","title":{"rendered":"Sintesis y reactividad e carbonilos dinucleares insaturados de metales de transicion conteniendo ligandos ciclopentadienilo"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Celedonio \u00e1lvarez Gonz\u00e1lez <\/strong><\/h2>\n<p>En la presente investigaci\u00f3n se han sisntetizado diferentes complejos dinucleares ciclopentadien\u00edlicos de metales de transici\u00f3n (principalmente d emo y fe) con distintos ligandos puente f\u00f3sforo-dadores (pph2, p(oet)2, op(oe)2) y diferentes \u00f3rdenes de enlace metal-metal.  dichas especies se han generado a trav\u00e9s de reacciones de descarbonilaci\u00f3n, oxidaci\u00f3n o reducci\u00f3n de precursores apropiados, donde los procesos de formaci\u00c2\u00bfon de enlaces metal-metal compiten con procesos de activaci\u00f3n de nelaces (p-o, c-h, p-h, etc&#8230;) En los ligandos coordinados.  algunos de los nuevos compuestos preparados han resultado altamente reactivos, entre los que pueden destacerse el dicarbonio (mo2cp2(u-op (oet)2) (u-p(oet)2) (co)2), el ani\u00f3n (fe2cp2 (u-pph2) (co)2), el cati\u00f3n (fecp2 (u-pph2) (u-co) (co)2)+ o el radical (fecp2 (u-pph2) (u-co)(co)2).  el estudio de la reactividad de los compuestos  anteriores ha puesto de manifiesto no s\u00f3lo la utilidad de los puentes f\u00f3sforo-dadores empleados, sino el potencial de estos compuestos para la s\u00edntesis de nuevos compuestos organomet\u00e1licos, incluyendo los \u00abclusters\u00bb heteromet\u00e1licos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Sintesis y reactividad e carbonilos dinucleares insaturados de metales de transicion conteniendo ligandos ciclopentadienilo<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Sintesis y reactividad e carbonilos dinucleares insaturados de metales de transicion conteniendo ligandos ciclopentadienilo <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Celedonio \u00e1lvarez Gonz\u00e1lez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Oviedo<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 26\/01\/2001<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Victor Riera Alvarez<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal:  Royo gracia Miguel a. <\/li>\n<li>gabriel Garc\u00eda herbosa (vocal)<\/li>\n<li>Miguel \u00e1ngel Seco Garc\u00eda (vocal)<\/li>\n<li>Fernando Villafa\u00f1e gonalez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Celedonio \u00e1lvarez Gonz\u00e1lez En la presente investigaci\u00f3n se han sisntetizado diferentes complejos dinucleares ciclopentadien\u00edlicos de metales de [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[863,2587,8846,17,20],"tags":[184788,184791,39530,25433,184790,184789],"class_list":["post-88602","post","type-post","status-publish","format-standard","hentry","category-compuestos-organometalicos","category-elementos-de-transicion","category-oviedo","category-quimica","category-quimica-inorganica","tag-celedonio-alvarez-gonzalez","tag-fernando-villafane-gonalez","tag-gabriel-garcia-herbosa","tag-miguel-angel-seco-garcia","tag-royo-gracia-miguel-a","tag-victor-riera-alvarez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/88602","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=88602"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/88602\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=88602"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=88602"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=88602"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}