{"id":91340,"date":"2018-03-11T10:10:02","date_gmt":"2018-03-11T10:10:02","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sa%c2%adntesis-y-caracterizacion-de-nuevos-complejos-de-rutenio-conteniendo-ligandos-quirales-aplicaciones-en-catalisis-asimetrica\/"},"modified":"2018-03-11T10:10:02","modified_gmt":"2018-03-11T10:10:02","slug":"sa%c2%adntesis-y-caracterizacion-de-nuevos-complejos-de-rutenio-conteniendo-ligandos-quirales-aplicaciones-en-catalisis-asimetrica","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica-inorganica\/sa%c2%adntesis-y-caracterizacion-de-nuevos-complejos-de-rutenio-conteniendo-ligandos-quirales-aplicaciones-en-catalisis-asimetrica\/","title":{"rendered":"S\u00edntesis y caracterizaci\u00f3n de nuevos complejos de rutenio conteniendo ligandos quirales. aplicaciones en cat\u00e1lisis asim\u00e9trica."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Isabel Serrano N\u00fa\u00f1ez <\/strong><\/h2>\n<p>La tesis describe una serie de complejos de rutenio conteniendo ligandos quirales y su aplicaci\u00f3n en cat\u00e1lisis asim\u00e9trica.   por un lado se describe el complejo [rucl(bpea)((s)-binap)](bf4), donde (s)-binap es una difosfina quiral y bpea un ligando n-tridentado. Su aplicaci\u00f3n en cat\u00e1lisis de hidrogenaci\u00f3n asim\u00e9trica de sustratos olef\u00ednicos y carbon\u00edlicos, tanto en fase homog\u00e9nea como heterog\u00e9nea (tras inmovilizaci\u00f3n sobre soportes alumino-fosfato), ha mostrado excelentes resultados de conversi\u00f3n y excesos enantiom\u00e9ricos.  aparte, se ha desarrollado una familia de complejos con f\u00f3rmula [ru(t)(b)x], donde t representa un ligando tri-n-dentado, b una di-oxazolina quiral y x es cl o h2o. Se ha estudiado la actividad catal\u00edtica de los aquocomplejos con t = tpm en epoxidaciones, determin\u00e1ndose la influencia de los sustituyentes en b sobre el rendimiento y la quimioselectividad, favorecidos por interacciones de tipo \u00c2\u00bf-stacking. El uso de otros ligandos tridentados ha llevado a su rotura, habi\u00e9ndose caracterizado sin embargo los correspondientes complejos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>S\u00edntesis y caracterizaci\u00f3n de nuevos complejos de rutenio conteniendo ligandos quirales. aplicaciones en cat\u00e1lisis asim\u00e9trica.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 S\u00edntesis y caracterizaci\u00f3n de nuevos complejos de rutenio conteniendo ligandos quirales. aplicaciones en cat\u00e1lisis asim\u00e9trica. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Isabel Serrano N\u00fa\u00f1ez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Girona<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 23\/01\/2009<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Antoni Llobet Dalmases<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Jos\u00e9 oriol Rossell alfonso <\/li>\n<li>teodor Parella coll (vocal)<\/li>\n<li>diego Luna Martinez (vocal)<\/li>\n<li>Fernando Bozoglian tatlian (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Isabel Serrano N\u00fa\u00f1ez La tesis describe una serie de complejos de rutenio conteniendo ligandos quirales y su [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[2746,18809,20],"tags":[29185,69284,123159,189265,28726,78288],"class_list":["post-91340","post","type-post","status-publish","format-standard","hentry","category-catalisis","category-girona","category-quimica-inorganica","tag-antoni-llobet-dalmases","tag-diego-luna-Martinez","tag-fernando-bozoglian-tatlian","tag-isabel-serrano-nunez","tag-jose-oriol-rossell-alfonso","tag-teodor-parella-coll"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/91340","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=91340"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/91340\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=91340"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=91340"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=91340"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}