{"id":95746,"date":"2009-01-09T00:00:00","date_gmt":"2009-01-09T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/towards-highly-efficient-ligands-for-asymmetric-hydrogenations-a-covalent-modular-approach-and-investigations-into-bioinspired-supramolecular-strategies\/"},"modified":"2009-01-09T00:00:00","modified_gmt":"2009-01-09T00:00:00","slug":"towards-highly-efficient-ligands-for-asymmetric-hydrogenations-a-covalent-modular-approach-and-investigations-into-bioinspired-supramolecular-strategies","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/estereoquimica-y-analisis-conformacional\/towards-highly-efficient-ligands-for-asymmetric-hydrogenations-a-covalent-modular-approach-and-investigations-into-bioinspired-supramolecular-strategies\/","title":{"rendered":"Towards highly efficient ligands for asymmetric hydrogenations: a covalent modular approach and investigations into bioinspired supramolecular strategies"},"content":{"rendered":"<h2>Tesis doctoral de <strong> H\u00e9ctor Fern\u00e1ndez P\u00e9rez <\/strong><\/h2>\n<p>La preparaci\u00f3n de nuevos ligandos quirales p-op (fosfina-fosfinitos y fosfina-fosfitos), facilmente preparador con una estrategia sint\u00e9tica en dos etapas desde una aproximaci\u00f3n covalente, es descrita en la presente tesis doctoral. El mejor catalizador de la serie ha desmostrado tener propiedades catal\u00edticas excelntes en la hidrogenaci\u00f3n asim\u00e9trica catalizada por rodio de una amplia variedad de olefinas funcionalizadas. El resultado excelente y el dise\u00f1o modular de los ligandos sintetizados hacen \u00e9stos muy atractivos para futuras aplicaciones. La presente tesis doctoral describe tambi\u00e9n la preparaci\u00f3n de nuevos ligandos quirales que pueden comportarse como catalizadores supramoleculares inspirados en el mecanismo de regulaci\u00f3n alost\u00e9rica de los enzimas.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Towards highly efficient ligands for asymmetric hydrogenations: a covalent modular approach and investigations into bioinspired supramolecular strategies<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Towards highly efficient ligands for asymmetric hydrogenations: a covalent modular approach and investigations into bioinspired supramolecular strategies <\/li>\n<li><strong>Autor:<\/strong>\u00a0 H\u00e9ctor Fern\u00e1ndez P\u00e9rez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Rovira i virgili<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/09\/2009<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Anton Vidal Ferrer<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Miguel \u00e1ngel Peric\u00ed\u00a0s brondo <\/li>\n<li>Antonio Pizzano mancera (vocal)<\/li>\n<li>carmen Claver cabrero (vocal)<\/li>\n<li>Jos\u00e9 daniel Carmona gascon (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de H\u00e9ctor Fern\u00e1ndez P\u00e9rez La preparaci\u00f3n de nuevos ligandos quirales p-op (fosfina-fosfinitos y fosfina-fosfitos), facilmente preparador con una [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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