{"id":97288,"date":"2018-03-11T10:17:46","date_gmt":"2018-03-11T10:17:46","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/supramolecular-chemistry-of-aryl-extended-calix-4-pyrroles\/"},"modified":"2018-03-11T10:17:46","modified_gmt":"2018-03-11T10:17:46","slug":"supramolecular-chemistry-of-aryl-extended-calix-4-pyrroles","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/macromoleculas\/supramolecular-chemistry-of-aryl-extended-calix-4-pyrroles\/","title":{"rendered":"Supramolecular chemistry of aryl extended calix [4] pyrroles"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Guzman Gil Ramirez <\/strong><\/h2>\n<p>La presente tesis consta de dos vertientes interrelacionadas. La primera se centra en intentar cuantificar experimentalmente la contribuci\u00f3n energ\u00e9tica en disoluci\u00f3n de la interacci\u00f3n ani\u00f3n-, mediante el uso de calix[4]pirroles aril substituidos en las posiciones meso- como mol\u00e9culas modelo. El trabajo realizado muestra que la interacci\u00f3n ani\u00f3n- es repulsiva para anillos con valores de esp negativos y a medida que el efecto electr\u00f3n atrayente de los sustituyentes aumenta la interacci\u00f3n se vuelve menos repulsiva, hasta que, cuando el valor de esp en el centro del anillo arom\u00e1tico es positivo la interacci\u00f3n se vuelve ligeramente atractiva. La segunda en el uso de estos receptores simples para obtener arquitecturas supramoleculares m\u00e1s complejas, y su autoensamblaje en capsulas. Los estudios muestran que calix[4]pirroles sustituidos con grupos urea en sus anillos arom\u00e1ticos se autoemsamblan en capsulas dim\u00e9ricas en presencia de un huesped adecuado como los n-\u00f3xidos de alquil aminas y piridinas en disolventes apolares.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Supramolecular chemistry of aryl extended calix [4] pyrroles<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Supramolecular chemistry of aryl extended calix [4] pyrroles <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Guzman Gil Ramirez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Rovira i virgili<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 19\/11\/2009<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Pablo Jose Ballester Balaguer<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: javier De mendoza sans <\/li>\n<li>Juan  r. Granja  guillan (vocal)<\/li>\n<li>nazario Martin leon (vocal)<\/li>\n<li>Alberto Tarraga tomas (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Guzman Gil Ramirez La presente tesis consta de dos vertientes interrelacionadas. La primera se centra en intentar [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[1387,18759],"tags":[8264,199432,15013,199433,37204,107244],"class_list":["post-97288","post","type-post","status-publish","format-standard","hentry","category-macromoleculas","category-rovira-i-virgili","tag-alberto-tarraga-tomas","tag-guzman-gil-ramirez","tag-javier-de-mendoza-sans","tag-juan-r-granja-guillan","tag-nazario-martin-leon","tag-pablo-jose-ballester-balaguer"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/97288","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=97288"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/97288\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=97288"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=97288"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=97288"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}