{"id":9774,"date":"1996-01-01T00:00:00","date_gmt":"1996-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/1996\/01\/01\/organoliticos-inestables-via-intercambio-cl-li-utilizacion-como-sintones\/"},"modified":"1996-01-01T00:00:00","modified_gmt":"1996-01-01T00:00:00","slug":"organoliticos-inestables-via-intercambio-cl-li-utilizacion-como-sintones","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/organoliticos-inestables-via-intercambio-cl-li-utilizacion-como-sintones\/","title":{"rendered":"Organoliticos inestables via intercambio cl-li. utilizacion como sintones."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Albert Guijarro Pastor <\/strong><\/h2>\n<p>En este trabajo se describe un procedimiento que permite la utilizacion de materiales organicos policlorados y alfa-clorooxigenados como equivalentes sinteticos de compuestos organicos polilitiados y alfa-oxigeno litiados respectivamente, interesantes desde el punto de vista sintetico organico, y dificilmente accesibles por otras rutas.Este proceso se basa en la utilizacion conjunta de un procedimiento de litiacion catalizado por un areno, y condiciones de reaccion con electrofilos tipo barbier. En estas condiciones se prepararon equivalentes sinteticos del dilitiometano, ch2li2: 1,3-dilitiopropeno, lich2-ch=chli; 2,3-dilitiopropeno, ch2cli=ch2li; 1,4-dilitiobuteno-2; 1,4-dilitiobutino-2, lich2ccch2li; y litiometil etil eter. Etoch2li. Se describen los diferentes procedimientos utilizados para obtener productos de reaccion de los mismos con determinados electrofilos, mostrando de este modo la utilidad sintetica del proceso.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Organoliticos inestables via intercambio cl-li. utilizacion como sintones.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Organoliticos inestables via intercambio cl-li. utilizacion como sintones. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Albert Guijarro Pastor <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Alicante<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1996<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Miguel \u00e1ngel Yus Astiz<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Alexander Mckillop <\/li>\n<li>Angel Pericas M. (vocal)<\/li>\n<li>Ulises Acu\u00f1a (vocal)<\/li>\n<li>Carmen Najera (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Albert Guijarro Pastor En este trabajo se describe un procedimiento que permite la utilizacion de materiales organicos [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[19166,6775,17,416],"tags":[33182,33183,33184,6658,5623,33185],"class_list":["post-9774","post","type-post","status-publish","format-standard","hentry","category-alicante","category-organometalicos","category-quimica","category-quimica-organica","tag-albert-guijarro-pastor","tag-alexander-mckillop","tag-angel-pericas-m","tag-carmen-najera","tag-miguel-angel-yus-astiz","tag-ulises-acuna"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/9774","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=9774"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/9774\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=9774"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=9774"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=9774"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}