{"id":99223,"date":"2018-03-11T10:20:17","date_gmt":"2018-03-11T10:20:17","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sa%c2%adntesis-y-caracterizacion-de-ligandos-ha%c2%adbridos-n-pirazol-p-fosfina-y-n-pirazol-op-fosfinito-y-su-reactividad-con-metales-de-transicion\/"},"modified":"2018-03-11T10:20:17","modified_gmt":"2018-03-11T10:20:17","slug":"sa%c2%adntesis-y-caracterizacion-de-ligandos-ha%c2%adbridos-n-pirazol-p-fosfina-y-n-pirazol-op-fosfinito-y-su-reactividad-con-metales-de-transicion","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sa%c2%adntesis-y-caracterizacion-de-ligandos-ha%c2%adbridos-n-pirazol-p-fosfina-y-n-pirazol-op-fosfinito-y-su-reactividad-con-metales-de-transicion\/","title":{"rendered":"S\u00edntesis y caracterizaci\u00f3n de ligandos h\u00edbridos n-pirazol, p-fosfina y n-pirazol, op-fosfinito y su reactividad con metales de transici\u00f3n"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Sergio Mu\u00f1oz Hernandez <\/strong><\/h2>\n<p>La presente tesis doctoral aporta la s\u00edntesis y caracterizaci\u00f3n de una familia de ligandos org\u00e1nicos h\u00edbridos n-pirazol, p-fosfina, n-pirazol op-fosfinito y n-pirazol, o-alcohol y el estudio de su reactividad con diversos metales de transici\u00f3n, se han sintetizado un total de 13 ligandos h\u00edbridos: cuatro ligandos n-pirazol, o-alcohol (la1-la4), cuatro ligandos n-pirazol, op-fosfinito (lop1-lop4) y cinco ligandos n-pirazol, p-fosfina (lp0-lp4). Adem\u00e1s, se han sintetizado cuatro ligandos precursores n-pirazol, cl-cloruro (lcl1-lcl4), necesarios para sintetizar los ligandos lp.  con los ligandso lop se ha ensayado la reactividad de ru(ii), rh(i) y pd(ii) y se han obtenido diferentes tipos de coordinaci\u00f3n seg\u00fan el metal utilizado. Con los ligandos lp se ha ensayado la reactividad con pd(ii), pt(ii), cu(i), ag(i) y au(i) y se ha obtenido una gran diversidad estructural. Por \u00faltimo, con el ligando la4 se ha estudiado la reactivivdad con pd(ii), zn(ii) y cu(ii). En los complejos de pd(ii) y zn(ii) el ligando act\u00faa de forma neutra, mientras que en el del cu(ii) act\u00faa como ani\u00f3nico por la p\u00e9rdida del prot\u00f3n del grupo alcohol. En conjunto se han sintetizado un total de 31 complejos. la caracterizaci\u00f3n de los complejos se ha realizado utilizando diversas t\u00e9cnicas: an\u00e1lisis elemental, conductividad, espectrometr\u00eda de masas, espectroscopia ir, rmn (monodimensional y bidimensional) y difracci\u00f3n de rayos x en monocristal. Adem\u00e1s, para el complejo de cu(ii) se han realizado estudios magn\u00e9ticos (susceptibilidad molar y epr).<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>S\u00edntesis y caracterizaci\u00f3n de ligandos h\u00edbridos n-pirazol, p-fosfina y n-pirazol, op-fosfinito y su reactividad con metales de transici\u00f3n<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 S\u00edntesis y caracterizaci\u00f3n de ligandos h\u00edbridos n-pirazol, p-fosfina y n-pirazol, op-fosfinito y su reactividad con metales de transici\u00f3n <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Sergio Mu\u00f1oz Hernandez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Aut\u00f3noma de barcelona<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 17\/02\/2010<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Josep Ros Badosa<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: julio Real obradors <\/li>\n<li>merce Font bardia (vocal)<\/li>\n<li>  (vocal)<\/li>\n<li>  (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Sergio Mu\u00f1oz Hernandez La presente tesis doctoral aporta la s\u00edntesis y caracterizaci\u00f3n de una familia de ligandos [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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